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Howdy,
Not through Virtualmin... but you can do it manually, from the command line.
If you edit /etc/postgrey/whitelist_recipients.local, you can add domains and email addresses that should be whitelisted.
After making changes to it, restart Postgrey, and you should be all set!
-Eric
That should do the trick : ) Many thanks.
For the record, in CentOS 5, I found it under /etc/postfix/postgrey_whitelist_recipients