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What happens when you try? Do you get any error messages?
Take a look in $HOME/logs/error_log for any PHP errors, and /var/log/mail.log for any errors with the email itself.
-Eric
checked the /var/log/mail.log see results below
Feb 12 14:39:06 hosting postfix/sendmail[17730]: fatal: usage: sendmail [options] Feb 12 14:40:01 hosting postfix/pickup[15794]: 56267DA57: uid=113 from= Feb 12 14:40:01 hosting postfix/cleanup[17785]: 56267DA57: message-id=20100212144001.56267DA57@hosting.exeter-it.co.uk Feb 12 14:40:01 hosting postfix/qmgr[8880]: 56267DA57: from=smmsp@exeter-it.co.uk, size=688, nrcpt=1 (queue active) Feb 12 14:40:01 hosting postfix/error[17787]: 56267DA57: to=root@exeter-it.co.uk, orig_to=, relay=none, delay=0.11, delays=0.07/0.01/0/0.03, dsn=5.0.0, status=bounced (User unknown in virtual alias table) Feb 12 14:40:01 hosting postfix/cleanup[17785]: 67BDBDA58: message-id=20100212144001.67BDBDA58@hosting.exeter-it.co.uk Feb 12 14:40:01 hosting postfix/bounce[17788]: 56267DA57: sender non-delivery notification: 67BDBDA58 Feb 12 14:40:01 hosting postfix/qmgr[8880]: 67BDBDA58: from=<>, size=2524, nrcpt=1 (queue active) Feb 12 14:40:01 hosting postfix/qmgr[8880]: 56267DA57: removed Feb 12 14:40:01 hosting postfix/error[17787]: 67BDBDA58: to=smmsp@exeter-it.co.uk, relay=none, delay=0.05, delays=0.02/0/0/0.03, dsn=5.0.0, status=bounced (User unknown in virtual alias table) Feb 12 14:40:01 hosting postfix/qmgr[8880]: 67BDBDA58: removed Feb 12 14:44:06 hosting postfix/sendmail[17883]: fatal: usage: sendmail [options] Feb 12 14:49:06 hosting postfix/sendmail[18023]: fatal: usage: sendmail [options] Feb 12 14:54:06 hosting postfix/sendmail[18172]: fatal: usage: sendmail [options] Feb 12 15:00:01 hosting postfix/pickup[15794]: 855FADA57: uid=113 from= Feb 12 15:00:01 hosting postfix/cleanup[18310]: 855FADA57: message-id=20100212150001.855FADA57@hosting.exeter-it.co.uk Feb 12 15:00:01 hosting postfix/qmgr[8880]: 855FADA57: from=smmsp@exeter-it.co.uk, size=688, nrcpt=1 (queue active) Feb 12 15:00:01 hosting postfix/error[18312]: 855FADA57: to=root@exeter-it.co.uk, orig_to=, relay=none, delay=0.12, delays=0.07/0.01/0/0.04, dsn=5.0.0, status=bounced (User unknown in virtual alias table) Feb 12 15:00:01 hosting postfix/cleanup[18310]: 9AC3CDA58: message-id=20100212150001.9AC3CDA58@hosting.exeter-it.co.uk Feb 12 15:00:01 hosting postfix/qmgr[8880]: 9AC3CDA58: from=<>, size=2524, nrcpt=1 (queue active) Feb 12 15:00:01 hosting postfix/bounce[18313]: 855FADA57: sender non-delivery notification: 9AC3CDA58 Feb 12 15:00:01 hosting postfix/qmgr[8880]: 855FADA57: removed Feb 12 15:00:01 hosting postfix/error[18312]: 9AC3CDA58: to=smmsp@exeter-it.co.uk, relay=none, delay=0.06, delays=0.03/0/0/0.03, dsn=5.0.0, status=bounced (User unknown in virtual alias table) Feb 12 15:00:01 hosting postfix/qmgr[8880]: 9AC3CDA58: removed Feb 12 15:00:35 hosting postfix/sendmail[18619]: fatal: usage: sendmail [options] Feb 12 15:02:43 hosting dovecot: ssl-build-param: SSL parameters regeneration completed
Still can't send e-mails from php scripts please help.